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Class 12 · Physics · Part 2

Chapter 14: Semiconductor Electronics: Materials, Devices and Simple Circuits

Revision notes, practice numericals, a question bank, assertion and reason questions and answers to the NCERT questions. Tap a group to open it; opening one closes the others.

14.1–14.2Energy bands and classification of solidsMetals, semiconductors and insulators

Conductivity

  • Metals: ρ ~ 10⁻² to 10⁻⁸ Ω m. Semiconductors: ρ ~ 10⁻⁵ to 10⁶ Ω m (Si, Ge, GaAs…). Insulators: ρ ~ 10¹¹ to 10¹⁹ Ω m.

Energy bands

  • In a solid the levels form the valence band (filled) and the conduction band separated by an energy gap E_g. In a metal the bands overlap or the conduction band is partly filled. In an insulator E_g > 3 eV. In a semiconductor E_g < 3 eV: diamond 5.4 eV, silicon 1.1 eV and germanium 0.7 eV.
  • Light of wavelength λ ≤ 1240/E_g (nm) can lift an electron across the gap (about 1130 nm for Si).
conductionvalence (overlap)MetalconductionvalenceEg ≈ 1 eVSemiconductorconductionvalenceEg > 3 eVInsulator
Energy bands in a metal, a semiconductor and an insulator.
14.3Intrinsic semiconductorsElectrons and holes

Electron–hole pairs

  • A pure crystal such as Si or Ge has four valence electrons per atom, each in a covalent bond. At 0 K it is an insulator. At higher temperature some bonds break: a free electron and a hole (a vacant bond which behaves as a positive carrier) are produced.
  • In an intrinsic semiconductor nₑ = nₕ = nᵢ. The conductivity rises with temperature, so the resistance decreases as the temperature increases (opposite to a metal). The current has two parts: electrons in the conduction band and holes in the valence band.
14.4Extrinsic semiconductorsn-type and p-type

Doping

  • n-type: a pentavalent dopant (P, As, Sb) gives an extra electron, so electrons are the majority carriers and holes the minority: nₑ ≫ nₕ.
  • p-type: a trivalent dopant (B, Al, In) creates a vacancy (hole): holes are the majority carriers and electrons the minority: nₕ ≫ nₑ.
  • In both cases the semiconductor is electrically neutral, and at a given temperature nₑ nₕ = nᵢ².
14.5–14.6The p-n junction and the diodeDepletion region and bias

p-n junction

  • When p and n regions are joined, electrons diffuse from n to p and holes from p to n (diffusion current). This leaves immobile positive ions on the n-side and negative ions on the p-side, forming the depletion region (about 0.1 μm wide) and a barrier potential V₀ (about 0.7 V for Si, 0.3 V for Ge). The field produces a drift current in the opposite direction; at equilibrium the net current is zero.
pndepletionregion− +− +− +built-in potential V₀ (n side higher)immobile ions: negative on the p side, positive on the n side
The p-n junction and its depletion region.

Biasing

  • Forward bias (p to +): the barrier falls to V₀ − V, the depletion region narrows and a large current flows (majority carriers, minority-carrier injection). The current rises sharply above the cut-in voltage (~0.7 V for Si, ~0.2 V for Ge).
  • Reverse bias: the barrier rises to V₀ + V, the depletion region widens, and only a very small reverse saturation current (μA, by minority carriers) flows, nearly independent of V until breakdown.
  • The forward resistance is low and the reverse resistance very high; the dynamic resistance r_d = ΔV/ΔI.
VIcut-in ≈ 0.7 V (Si)reverse: small currentforward current rises sharply above the cut-in voltage
I–V characteristic of a junction diode.
14.7RectifiersHalf-wave, full-wave and the filter

Rectification

  • Half-wave rectifier: one diode conducts in one half of the cycle only; the output frequency equals the input frequency (50 Hz).
  • Full-wave rectifier: a centre-tap transformer with two diodes (or a bridge of four diodes) gives an output in both halves; the output frequency is twice the input (100 Hz).
  • A capacitor filter across the load charges to the peak voltage and discharges slowly, reducing the ripple. The reverse breakdown voltage of the diode must exceed the peak input voltage.
input achalf-wave output
Half-wave rectifier: input and output waveforms.
Quick referenceFormulas at a glanceRevise before the exam

Key results

  • nₑ = nₕ = nᵢ (intrinsic); nₑ nₕ = nᵢ² (doped)
  • E_g: C 5.4 eV, Si 1.1 eV, Ge 0.7 eV
  • Forward barrier V₀ − V; reverse V₀ + V
  • Output frequency: half-wave f, full-wave 2f

Common mistakes

  • Calling n-type semiconductors negatively charged (they are neutral).
  • Saying that the diode current in reverse bias is due to majority carriers.
  • Mixing up trivalent (p-type) and pentavalent (n-type) dopants.
  • Using the input frequency for the full-wave rectifier output.